Evidence for dissolved polymeric mercury(II)-sulfur complexes?
نویسندگان
چکیده
منابع مشابه
The first photocrystallographic evidence for light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes.
Light-induced metastable linkage isomers of trans-[Ru(NH(3))(4)Cl(SO(2))]Cl and trans-[Ru(NH(3))(4)(H(2)O)(SO(2))](C(6)H(5)SO(3))(2) have been identified for the first time using photocrystallographic methods. In both linkage isomers the SO(2) ligand is side bound, but the Ru-O and Ru-S distances are considerably longer and almost equal in the trans-H(2)O isomer. DFT calculations confirm that b...
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ژورنال
عنوان ژورنال: Chemical Geology
سال: 2007
ISSN: 0009-2541
DOI: 10.1016/j.chemgeo.2007.05.013